Lee Goldberg of Main Title Heaven has compiled the main title sequences or opening credits of great and not so great TV series.
This one above [YouTube] is from the Man From U.N.C.L.E. [wiki] Season 1 Opening.
Link - via Yahoo! Picks
U.N.C.L.E. is a classic! Man ... or Astro-Man? covered the theme some years ago, and did a great job as well.
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